Synthesis and photophysical properties of new Eu(III) complex

Mustafa Burak Çoban

Öz


In this study, the new Eu(III) complex was hydrothermally synthesized using oxygen donor ligand and characterized by single crystal X-ray diffraction, elemental analysis, solid UV-Vis spectroscopy, FT-IR and photoluminescence properties.  The crystal structure analysis of complex [C7H9EuO9S](1) indicates that the central lanthanide ions are coordinated by eight oxygen atoms in which six oxygen atoms from four ssa-anionic ligands and two oxygen atoms from a coordinated water molecules.  Complex 1 bridged by oxygen atoms from carboxyl and sulfonate groups of the ssa- ligands are formed in 1D chains.  The 1D chains are linked together with ligand ssa- to form a 2D wave-like layers.  All these wave-like layers are further interlinked via strong hydrogen bonding interaction resulting in 3D architecture.  Additionally, solid state photoluminescence properties of complex 1 have been investigated in room temperature.  The indirect energy transfer mechanism via an Antenna effect in complex 1 has been investigated in detail.


Tam Metin:

PDF

Referanslar


Oylumluoglu, G., Coban, M. B., Kocak, C., Aygun, M. & Kara, H., 2-and 1-D coordination polymers of Dy(III) and Ho(III) with near infrared and visible luminescence by efficient charge-transfer antenna ligand, J. Mol. Struct., 1146, 356–364, (2017).

Yahsi, Y., Ozbek, H., Aygun, M. & Kara, H., Crystal structure and photoluminescence properties of a new Cd II coordination polymer catena -poly[bis[4-bromo-2-({[2-(pyrrolidin-1-yl)ethyl]imino}methyl)phenolato-κ 3 N , N ′, O ]di-μ 3 -chlorido-di-μ 2 -chlorido-bis(methanol-κ O )tricadmium(II)], Acta Crystallogr. Sect. C Struct. Chem., 72, 426–431, (2016).

Güngör, E., Cu4O4 Kübik Formdaki Bakır (II) Kompleksinin Yapısal ve Fotolüminesans Özelliklerinin İncelenmesi, Süleyman Demirel Üniversitesi Fen Bilim. Enstitüsü Dergisi, 0, 10, (2017).

Gungor, E., 3-D polymeric structure formed by hydrogen bonds of copper (II) complex, Mol. Cryst. Liq. Cryst., 642, 21–28 (2017).

Gungor, E., A new stepped tetranuclear copper(II) complex: Synthesis, crystal structure and photoluminescence properties, Acta Crystallogr. Sect. C Struct. Chem., 73, 393–398, (2017).

Coban, M. B., Kocak, C., Kara, H., Aygun, M. & Amjad, A., Magnetic properties and sensitized visible and NIR luminescence of Dy III and Eu III coordination polymers by energy transfer antenna ligands, Mol. Cryst. Liq. Cryst., 648, 202–215, (2017).

Li, X., Lu, Y., Bing, Y. & Zha, M., Synthesis , Photoluminescent , and Magnetic Properties of Two Lanthanide Sulfosalicylate Complexes, Synth. React. Inorganic, Met. Nano-Metal Chem., 42, 698–704, (2012).

Zhou, R.-S. et al., Syntheses, structures, luminescence, and magnetism of four 3D lanthanide 5-sulfosalicylates, J. Solid State Chem., 181, 567–575, (2008).

Coban, M. B., Amjad, A., Aygun, M. & Kara, H., Sensitization of HoIII and SmIII luminescence by efficient energy transfer from antenna ligands: Magnetic, visible and NIR photoluminescence properties of GdIII, HoIII and SmIII coordination polymers, Inorg. Chim. Acta, 455, 25–33, (2017).

Ay, B., Yildiz, E. & Kani, İ., Two novel isostructural and heteroleptic Nd(III) and Dy(III)-organic frameworks constructed by 2,5-pyridinedicarboxylic acid and in situ generated 2-pyridinecarboxylic acid: Hydrothermal synthesis, characterization, photoluminescence properties and hetero, Polyhedron, 130, 165–175, (2017).

Allendorf, M. D., Bauer, C. A., Bhakta, R. K. & Houk, R. J. T., Luminescent metal–organic frameworks, Chem. Soc. Rev., 38, 1330–1352, (2009).

Dang, S. et al., Near-Infrared Luminescence from Sol−Gel Materials Doped with Holmium(III) and Thulium(III) Complexes, J. Phys. Chem. C, 112, 13240–13247, (2008).

Beeby, A. et al., Luminescence imaging microscopy and lifetime mapping using kinetically stable lanthanide(III) complexes, J. Photochem. Photobiol. B.,57, 83–89, (2000).

Zhao, J. et al., Magnetic and luminescent properties of lanthanide coordination polymers with asymmetric biphenyl-3,2′,5′-tricarboxylate, Dalt. Trans., 44, 14424–14435, (2015).

Yenikaya, C., Sari, M., Lkimen, H., Bülbül, M. & Büyükgüngör, O., Synthesis and characterization of a novel amino salicylato salt and its Cu(II) complex and their inhibition studies on carbonic anhydrase isoenzymes, Polyhedron, 30, 535–541, (2011).

Lu, Z. D., Wen, L. L., Yao, J., Zhu, H. H. & Meng, Q. J., Two types of novel layer framework structures assembled from 5-sulfosalicylic acid and lanthanide ions, Crystengcomm, 8, 847–853, (2006).

Starynowicz, P., Synthesis and crystal structure of europium(II) dihydrogen bis(sulfosalicylate) pentahydrate [Eu(C7H5O6S)2(H2O)5]∞, J. Alloys Compd.,305, 117–120, (2000).

Clark, R. C. & Reid, J. S., The analytical calculation of absorption in multifaceted crystals, Acta Crystallogr. Sect. A, 51, 887–897, (1995).

Dolomanov, O. V., Bourhis, L. J., Gildea, R. J., Howard, J. A. K. & Puschmann, H., OLEX2: A complete structure solution, refinement and analysis program, J. Appl. Crystallogr., 42, 339–341, (2009).

Sheldrick, G. M., A short history of SHELX, Acta Crystallogr. Sect. A Found. Crystallogr., 64, 112–122, (2007).

Spek, A. L., Structure validation in chemical crystallography, Acta Crystallogr. Sect. D Biol. Crystallogr., 65, 148–155, (2009).

Li, X., Xie, Z., Lin, J. & Cao, R., Lanthanide-organic frameworks constructed from multi-functional ligands: Syntheses, structures, near-infrared and visible photoluminescence properties, J. Solid State Chem.,182, 2290–2297, (2009).

Coban, M. B., Erkarslan, U., Oylumluoglu, G., Aygun, M. & Kara, H., Hydrothermal synthesis, crystal structure and Photoluminescent properties; 3D Holmium(III) coordination polymer, Inorg. Chim. Acta, 447, 87–91, (2016).

Acar, Y., Photoluminescence properties of Gd(III) and Ce(III) lanthanide based metal organic frameworks, Anadolu Univ. J. Sci. Technol. A - Appl. Sci. Eng.,17, 754–754, (2016).

Ilmi, R. & Iftikhar, K., Structure elucidation by sparkle/RM1, effect of lanthanide contraction and photophysical properties of lanthanide(III) trifluoroacetylacetonate complexes with 1,10-phenanthroline, J. Photochem. Photobiol. A Chem., 325, 68–82, (2016).

Zhou, X. et al., Eu(III) and Tb(III) Complexes with the Nonsteroidal Anti-Inflammatory Drug Carprofen: Synthesis, Crystal Structure, and Photophysical Properties, Inorg. Chem., 53, 12275–12282, (2014).

Shen, H.-Y., Wang, W.-M., Gao, H.-L. & Cui, J.-Z., Near-infrared luminescence and SMM behaviors of a family of dinuclear lanthanide 8-quinolinolate complexes, RSC Adv., 6, 34165–34174, (2016).

Feng, X. et al., Reticular three-dimensional 3d–4f frameworks constructed through substituted imidazole-dicarboxylate: syntheses, luminescence and magnetic properties study, Dalt. Trans., 44, 804–816, (2015).

Han, Y., Fu, L., Mafra, L. & Shi, F.-N., Hydrothermal synthesis, crystal structures and photoluminescence properties of mixed europium–yttrium organic frameworks, J. Solid State Chem., 186, 165–170, (2012).

Teixeira, J. A. et al., Synthesis, thermoanalytical, spectroscopic study and pyrolysis of solid rare earth complexes (Eu, Gd, Tb and Dy) with p-aminobenzoic acid, J. Anal. Appl. Pyrolysis, 121, 267–274, (2016).

Liu, D. D. et al., Effect of ring coordination of pyridine-3,5-dicarboxylate and metatungstate to Ln ions on metatungstate structure: Synthesis, structure and optical property of four new compounds, J. Solid State Chem., 184, 1355–1360, (2011).

Xu, W., Zhang, C.-J., Wang, H. & Wang, Y., Two Novel Two-Dimensional Lanthanide (III) Coordination Polymers Constructed from Isonicotinic Acid and Iminodiacetic Acid: Synthesis, Structure, and Luminescence Properties, J. Clust. Sci., 28, 2005–2015, (2017).

Liu, C.-B., Li, Q., Wang, X., Che, G.-B. & Zhang, X.-J., A series of lanthanide (III) coordination polymers derived via in situ hydrothermal decarboxylation of quinoline-2,3-dicarboxylic acid, Inorg. Chem. Commun., 39, 56–60, (2014).

Wu, Q. R. et al., A series of lanthanide coordination polymers with 4′-(4- carboxyphenyl)-2,2′:6′,2″-terpyridine: Syntheses, crystal structures and luminescence properties, Inorg. Chem. Commun., 14, 484–488, (2011).

Ma, P. et al., Double-malate bridging tri-lanthanoid cluster encapsulated arsenotungstates: syntheses, structures, luminescence and magnetic properties, Dalt. Trans., 44, 11514–11523, (2015).

Jiao, C. et al., Lanthanide(III) oxalatophosphonates: syntheses, crystal structures and luminescence properties, Dalt. Trans., 43, 1542–1549, (2014).

Dang, S. et al., Syntheses, crystal structures and near-infrared luminescent properties of holmium (Ho) and praseodymium (Pr) ternary complexes, Inorg. Chem. Commun., 11, 531–534, (2008).

Dang, S. et al., Novel Holmium (Ho) and Praseodymium (Pr) ternary complexes with fluorinated-ligand and 4,5-diazafluoren-9-one, Mater. Lett., 65, 1642–1644, (2011).

Dang, S. et al., NIR-luminescence from ternary lanthanide [HoIII, Pr III and TmIII] complexes with 1-(2-naphthyl)-4,4,4- trifluoro-1,3-butanedionate, J. Lumin., 131, 1857–1863, (2011).


Refback'ler

  • Şu halde refbacks yoktur.


Telif Hakkı (c) 2017 MUSTAFA BURAK ÇOBAN

Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.