Single Crystal X-ray Structure Determination of N,N’-di(9-ethyl-9H-carbazole-3-yl)hydrazine

Ece Uzkara, Fahrettin Filiz, Orhan Zeybek, Erol Asker

Öz


The structure of N,N’-di(9-ethyl-9H-carbazole-3-yl)hydrazine has been determined by single crystal X-ray crystallography. No p···p interactions were observed among the molecules. The crystal packing is stabilized only by the week p···H-C interactions. The calculated values of the bond lengths and bond angles have been compared with those obtained from X-ray diffraction analyses. There is a good agreement between experimental and calculated values of the data, except the N1-N1 bond length and the angles around these atoms in the molecule.


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Referanslar


Hirschfeld, S., Assaying for a multiplicity of antigens or antibodies with a detection compound, US Patent 4514508 (1985).

Otieno, M. A., Baggs, R. B., Hayes J. D., Anders, M. W., Immunolocalization of microsomal glutathiones-transferase in Rat Tissues, Drug Metabolism and Disposition, 25, 12-20, (1997).

Haq, M. R., Kalatzis, V., Gubler, M. C., Town, M. M., Antignac, C., Van't Hoff W. G., Woolf, A. S., Immunolocalization of cystinosin, the protein defective in cystinosins, Journal of the American Society of Nephrology, 13, 2046-2051, (2002).

Comas, T. C., Tai, T., Kimmel, D., Scheithauer, B. W., Burger, P. C., Pearl, D. K., Jewell S. D., Yates, A. J., Immunohistochemical staining for ganglioside GD1b as a diagnostic and prognostic marker for primary human brain tumors, Neuro-oncology, 1, 261-267, (1999).

Peciuraite, V., Vaitkeviciene, V., Grigalevicius, S., Grazulevicius J. V., Jankauskas V., Di(9-alkylcarbazol-3-yl)arylamines as electroactive amorphous materials for optoelectronics, Monatshefte für Chemie, 137, 1053-1062, (2006).

Puodziukynaite, E., Burbulis, E., Grazulevicius, J. V., Getautis V., Jankauskas J., Carbazole-based bis(enamines) as effective charge-transporting amorphous molecular materials, Synthetic Metals, 158, 993-998, (2008).

Mishra, A. K., Jacob J., Mullen, K., Synthesis of aminocarbazole-anthraquinone fused dyes and polymers, Dyes and Pigments, 75, 1-10, (2007).

Gibson, H. W., Olin G. R., Pochan, J. M., Linear free energy relationships. Part 10. Synthesis, thermal, spectral, electrochemical, and hole transport (conduction) properties of some novel carbazole derivatives, Journal of Chemical Society, Perkin Transactions II, 1267-1273, (1981).

Grigoras, M.; Antonoaia, N.C., Synthesis and characterization of some carbazole-based imine polymers, European Polymer Journal, 41, 1079-1089, (2005).

Segura, J. L., The chemistry of electroluminescent organic materials, Acta Polymerica, 1998, 49, 319-344, (1998).

SIR92 - Altomare, A., Cascarano, G., Giacovazzo C., Guagliardi, A., Completion and refinement of crystal structures with SIR92, Journal of Applied Crystallography, 26, 343-350, (1993).

Sheldrick, G. M., SHELXL-97, Program for Crystal Structure Refinement, University of Göttingen, Germany, (1997).

Farrugia, L. J., WinGX suite for small-molecule single-crystal crystallography, Journal of Applied Crystallography, 32, 837-838, (1999).

Burkert, U., Allinger, N. L., Molecular Mechanics, ACS Monograph, No. 177 (1982).

Allinger, N. L., Conformational analysis. 130. MM2. A hydrocarbon force field utilizing V1 and V2 torsional terms, Journal of the American Chemical Society, 99, 8127-8134, (1977).

Dewar, M. J. S.; Zoebisch, E. G.; Healey E. F.; Stewart, J. J. P., Development and use of quantum mechanical molecular models. 76. AM1: a new general purpose quantum mechanical molecular model, Journal of the American Chemical Society, 107, 3902-3909, (1985).

HyperChem 8.05 for Windows, Hypercube Inc., 1115 NW 4th Street, Gainesville, FL 32601, USA., (2008).

Asker, E., Masnovi, J.,1,3-Bis(9-ethylcarbazol-3-yl)propane, Acta Crystallographica Section E, 61, o2781-o2783, (2005).

Hang, Y.-C., Chen M.-D., Wang Y., 9-Ethyl-3-(2-methylbenzoyl)-9 H-carbazole, Acta Crystallographica Section E, E65, o279, (2009).

Portilla, J., Cobo, J., de la Torre, J. M., Low J. N., Glidewell, C., N,N’-Bis(isonicotinoyl)hydrazine dihydrate at 120 (2) K: a three-dimentional framework built from N-H…O, O-H…O, O-H…N and C-H…O hydrogen bonds, Acta Crystallographica Section E, E63, o1687-o1690, (2007).

Zheng P.-W., Zhao B., N,N’-Bis(9-anthracenylidene)hydrazine, Acta Crystallographica Section E, E62, o2077-o2078, (2006).

Nesterov, V. V., Antipin, M. Y., Nesterov, V. N., Penn, B. G., Frazier D. O., Timofeeva T. V., Thermally stable imines as new potential nonlinear optical materials, Crystal Growth & Design, 4, 521-531, (2004).

a) Asker E., Masnovi, J., 9,9’-Diethyl-3,3’-di-9H-carbazolyl, Acta Crystallographica Section E, 2006, E62, o1133o1135, (2006); b) Asker E.; Masnovi, Bis(-ethylcarbazol-3yl)ethane, Acta Crystallographica Section E, 2006, E62, o1213-o1215, (2006).


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