Direct Blue 2 diazo-boyarmaddesinin sulu çözeltiden P(HEMA) nanopartiküller ile uzaklaştırılması

Aslı Göçenoğlu Sarıkaya

Öz


Bu çalışmada, Direct Blue 2 (DB2) diazo-boyar maddesinin poli(Hidroksietil metakrilat) [P(HEMA)] nanopartikülleri ile sulu çözeltiden giderimi çalışılmıştır.  Adsorpsiyona ortam pH’ının, sıcaklığın, başlangıç boya derişiminin ve temas süresinin etkileri incelenmiştir.  Optimum koşullar altında, 50 mg/mL başlangıç boya derişimi ve 2 mg polimer kullanılarak % 89.1 giderim elde edilmiştir.  Adsorpsiyon mekanizmasının anlaşılabilmesi için Langmuir, Freundlich ve Sips (Langmuir-Freundlich) izoterm sabitleri hesaplanmıştır.  Elde edilen verilere göre adsorpsiyonun Langmuir izoterm modeline uygun olduğu (R2: 0.993, Qmax: 27.1 mg/g) rapor edilmiştir.  Adsorpsiyon öncesi ve sonrası boya derişimleri UV-Vis spektrofotometresinde ölçülmüş, adsorpsiyon öncesi ve sonrası polimer FTIR ve SEM ile karakterize edilmiştir. 


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